Environmental Science and Pollution Research - Deposition particles can lead to blockage, odor, and corrosion of pipes, and the deposition process of suspended particles is particularly... 相似文献
Environmental Science and Pollution Research - In the context of global climate change, studies have focused on the ambient temperature and mortality of cardiovascular diseases (CVDs). However,... 相似文献
Environmental Science and Pollution Research - Understanding dynamic future changes in precipitation can provide prior information for nonpoint source pollution simulations under global warming.... 相似文献
Environmental Science and Pollution Research - In natural water bodies, numerous cyanobacteria have the potential to intracellularly synthesize cyanotoxins, among which microcystin (MC) is the... 相似文献
Environmental Science and Pollution Research - Soil acidification is a problem widely occurring worldwide, which severely threaten food security and agricultural sustainability. Calcium... 相似文献
Environmental Science and Pollution Research - Waste incineration is a process of full combustion reaction between waste and oxygen at high temperature. It is a new problem whether the special... 相似文献
Environmental Science and Pollution Research - As a kind of solid waste with a high silicon content, electrolytic manganese residue (EMR) can be utilized as silicon source by plants through... 相似文献
Microplastics pollution is becoming a major environmental issue, and exposure to microplastics has been associated with numerous adverse results to both the ecological system and humans. This work summarized the state-of-the-art developments in the breakdown of microplastics, including natural weathering, catalysts-assisted breakdown and biodegradation. Characterization techniques for microplastic breakdown involve scanning electron microscopy, Fourier infrared spectroscopy, X-ray photoelectron spectroscopy, etc. Bioavailability and adsorption capacity of microplastics may change after they are broken down, therefore leading to variety in microplastics toxicity. Further prospectives for should be focused on the determination and toxicity evaluation of microplastics breakdown products, as well as unraveling uncultivable microplastics degraders via cultivation-independent approaches. This work benefits researchers interested in environmental studies, particularly the removal of microplastics from environmental matrix.
Catalytic wet air oxidation (CWAO) coupled desalination technology provides a possibility for the effective and economic degradation of high salinity and high organic wastewater. Chloride widely occurs in natural and wastewaters, and its high content jeopardizes the efficacy of Advanced oxidation process (AOPs). Thus, a novel chlorine ion resistant catalyst B-site Ru doped LaFe1-xRuxO3-δ in CWAO treatment of chlorine ion wastewater was examined. Especially, LaFe0.85Ru0.15O3-δ was 45.5% better than that of the 6%RuO2@TiO2 (commercial carrier) on total organic carbon (TOC) removal. Also, doped catalysts LaFe1-xRuxO3-δ showed better activity than supported catalysts RuO2@LaFeO3 and RuO2@TiO2 with the same Ru content. Moreover, LaFe0.85Ru0.15O3-δ has novel chlorine ion resistance no matter the concentration of Cl− and no Ru dissolves after the reaction. X-ray diffraction (XRD) refinement, X-ray photoelectron spectroscopy (XPS), transmission electron microscope (TEM), and X-ray absorption fine structure (XAFS) measurements verified the structure of LaFe0.85Ru0.15O3-δ. Kinetic data and density functional theory (DFT) proved that Fe is the site of acetic acid oxidation and adsorption of chloride ions. The existence of Fe in LaFe0.85Ru0.15O3-δ could adsorb chlorine ion (catalytic activity inhibitor), which can protect the Ru site and other active oxygen species to exert catalytic activity. This work is essential for the development of chloride-resistant catalyst in CWAO.
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